Ruthenium oxyl radical complex containing o-quinone ligand detected by ESR measurements of spin trapping technique

Katsuaki Kobayashi; Hideki Ohtsu; Tohru Wada; Koji Tanaka

doi:10.1246/cl.2002.868

Ruthenium oxyl radical complex containing o-quinone ligand detected by ESR measurements of spin trapping technique

Katsuaki Kobayashi^*, Hideki Ohtsu, Tohru Wada, Koji Tanaka

^*この論文の責任著者

化学科

研究成果: ジャーナルへの寄稿 › 学術論文 › 査読

19 被引用数 (Scopus)

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Ruthenium-quinone complex containing an aqua ligand, [Ru^II(trpy)(35tBu₂Q)(OH₂)](ClO ₄)₂ (trpy=2,2′:6′,2″-terpyridine, 35tBu₂Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O^2- ligand to quinone ligand generating O^•- ligand.

本文言語	英語
ページ（範囲）	868-869
ページ数	2
ジャーナル	Chemistry Letters
号	8
DOI	https://doi.org/10.1246/cl.2002.868
出版ステータス	出版済み - 2002/08/05

ASJC Scopus 主題領域

化学一般

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10.1246/cl.2002.868

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title = "Ruthenium oxyl radical complex containing o-quinone ligand detected by ESR measurements of spin trapping technique",

abstract = "Ruthenium-quinone complex containing an aqua ligand, [RuII(trpy)(35tBu2Q)(OH2)](ClO 4)2 (trpy=2,2′:6′,2″-terpyridine, 35tBu2Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O2- ligand to quinone ligand generating O•- ligand.",

author = "Katsuaki Kobayashi and Hideki Ohtsu and Tohru Wada and Koji Tanaka",

year = "2002",

month = aug,

day = "5",

doi = "10.1246/cl.2002.868",

language = "英語",

pages = "868--869",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Oxford University Press",

number = "8",

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TY - JOUR

T1 - Ruthenium oxyl radical complex containing o-quinone ligand detected by ESR measurements of spin trapping technique

AU - Kobayashi, Katsuaki

AU - Ohtsu, Hideki

AU - Wada, Tohru

AU - Tanaka, Koji

PY - 2002/8/5

Y1 - 2002/8/5

N2 - Ruthenium-quinone complex containing an aqua ligand, [RuII(trpy)(35tBu2Q)(OH2)](ClO 4)2 (trpy=2,2′:6′,2″-terpyridine, 35tBu2Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O2- ligand to quinone ligand generating O•- ligand.

AB - Ruthenium-quinone complex containing an aqua ligand, [RuII(trpy)(35tBu2Q)(OH2)](ClO 4)2 (trpy=2,2′:6′,2″-terpyridine, 35tBu2Q=3,5-di-tert-butyl-1,2-benzoquinone) underwent deprotonation of an aqua ligand accompanied with intramolecular electron transfer from O2- ligand to quinone ligand generating O•- ligand.

UR - http://www.scopus.com/inward/record.url?scp=0037025484&partnerID=8YFLogxK

U2 - 10.1246/cl.2002.868

DO - 10.1246/cl.2002.868

M3 - 学術論文

AN - SCOPUS:0037025484

SN - 0366-7022

SP - 868

EP - 869

JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

Ruthenium oxyl radical complex containing o-quinone ligand detected by ESR measurements of spin trapping technique

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